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Monaco had never beaten the Spaniard in two prior meetings and it looked like he would fall again, but used a dominating final two sets to take the win and will now try to reach his third finals at this event.
He also reached the title contest of this clay-court event in 2010 at Santiago, and 2008.
Monaco will face off against Chardy in the semis, while Chela will do battle with Berlocq.
The 2012 Vina del Mar champion will collect $71,900.
The Russians can wrap up the best-of-five tie on Sunday with one more victory.
Russia, last year's Fed Cup runner-up to the Czech Republic, is a four-time Fed Cup champ and beat Spain in the final for its last title in 2008. The Russians own a 5-1 advantage against the Spaniards in Fed Cup play.
Biella, Italy (Sportsbook Betting Lines) - Italy and the Ukraine are surprisingly even after Saturday's opening singles matches of their Fed Cup quarterfinal. The matchups and home court clearly favored the Italians and Sara Errani gave the hosts the first point with a 6-2, 6-3 thumping of Kateryna Bondarenko. With former French Open champ Francesca Schiavone set for Saturday's second match, it appeared the Italians would have a big edge heading to Sunday.
Enter Lesia Tsurenko.
Italy has won three of the last six Fed Cup titles, including back-to-back crowns in 2009-10. The Italians are also 3-0 all-time against the Ukraine in Fed Cup play.
Huskers' Lucky hospitalized for undisclosed reason
LINCOLN, Neb. -- Nebraska running back Marlon Lucky was hospitalized Monday for undisclosed reasons after Lincoln police responded to a call at his residence.
The Nebraska athletic department said in a release Monday that Lucky was admitted Sunday night.
MySportsbook.com has the Cornhuskers listed at +2500 to win the BCS National Championship odds.
A nursing supervisor at the hospital said all questions about Lucky were being referred to the athletic department. The athletic department said there would be no further comment from the department or Lucky's family.
A Lincoln Police spokesman said officers responded to a call at Lucky's residence 11:30 p.m. Sunday. The spokesman said he didn't know Lucky's condition at the time he was taken to the hospital.
Lucky, from North Hollywood, Calif., started six games last season as a sophomore and was the team's second-leading rusher, with 728 yards and six touchdowns. He also caught 32 passes for 383 yards. He averaged 19.1 yards on eight kickoff returns.
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